Search results for " phase transitions"
showing 10 items of 24 documents
Raman study of the phase transitions sequence in pure WO3 at high temperature and in HxWO3 with variable hydrogen content
1999
Abstract An extensive investigation of the temperature dependence of Raman spectra has been carried out on WO 3 powders from room temperature to 800°C. In particular the orthorhombic-to-tetragonal phase transition occurring at about 740°C has been studied for the first time. The Raman active mode at 710 cm −1 of the orthorhombic phase disappears from the spectrum at temperature below the phase transition point and the Raman activity in the tetragonal phase results very low. A comparative study of hydrogenated tungsten bronzes H x WO 3 ( x ≤0.23), where the same transition sequence is driven by an increase of the proton concentration from x =0 to 0.23, reveals similar behaviour of the high f…
On critical properties of the Berry curvature in the Kitaev honeycomb model
2019
We analyse the Kitaev honeycomb model, by means of the Berry curvature with respect to Hamiltonian parameters. We concentrate on the ground-state vortex-free sector, which allows us to exploit an appropriate Fermionisation technique. The parameter space includes a time-reversal breaking term which provides an analytical headway to study the curvature in phases in which it would otherwise vanish. The curvature is then analysed in the limit in which the time-reversal-symmetry-breaking perturbation vanishes. This provides remarkable information about the topological phase transitions of the model. The Berry curvature in itself exhibits no singularities at criticality, nevertheless it distingui…
Wave-Vector Dependence of the Dynamics in Supercooled Metallic Liquids
2020
Physical review letters 125(5), 055701 (2020). doi:10.1103/PhysRevLett.125.055701
Thermodynamic, dynamic and transport properties of quantum spin liquid in herbertsmithite from experimental and theoretical point of view
2019
In our review we focus on the quantum spin liquid, defining the thermodynamic, transport and relaxation properties of geometrically frustrated magnets (insulators) represented by herbertsmithite $\rm ZnCu_{3}(OH)_6Cl_2$.
Heat Capacity and Entanglement Measure in a simple two-qubit model
2011
A simple two-qubit model showing Quantum Phase Transitions as a consequence of ground state level crossings is studied in detail. Using the Concurrence of the system as an entanglement measure and heat capacity as a marker of thermodynamical properties, an analytical expression giving the latter in terms of the former is obtained. A protocol allowing an experimental measure of entanglement is then presented and compared with a related proposal recently reported by Wie\'sniak, Vedral and Brukner
Size effect in phase transition kinetics
1988
The growth of a spontaneous lattice average magnetization in a magnetic system which is suddenly brought below the transition temperature is a stochastic process in which the very small fluctuations of the initial magnetization are amplified to a macroscopic size. The initial magnetization fluctuates in time around the zero average value because of the finite size of the system. As a consequence of the fluctuation-amplification phenomenon the nonlinear relaxation of the finite system is qualitatively different from that of the infinite one. The present paper studies this feature of phase-transition kinetics in the framework of a very simple model: the dynamical generalization of the spheric…
Order-Order Phase Transitions Induced by Supercritical Carbon Dioxide in Triblock Copolymer Thin Films
2019
We study the influence of supercritical carbon dioxide (scCO2) on the phase behavior of a cylinder-forming polystyrene-block-polybutadiene-b-polystyrenetriblock copolymer thin film. Solvent annealing with scCO2 can produce patterns with long-range order but these structures become unstable for thin films with small thicknesses. These results are in good agreement with self-consistent mean field calculations, which indicate that a drying transition occurs for thicknesses below the radius of gyration of the molecule.After decompression and solvent extraction, the initially swollen polymer nanostructure suffers a strong reduction in the average domain spacing, which has a deleterious effect on…
Ultrafast critical ground state preparation via bang-bang protocols
2020
The fast and faithful preparation of the ground state of quantum systems is a challenging task but crucial for several applications in the realm of quantum-based technologies. Decoherence poses a limit to the maximum time-window allowed to an experiment to faithfully achieve such desired states. This is of particular significance in critical systems, where the vanishing energy gap challenges an adiabatic ground state preparation. We show that a bang-bang protocol, consisting of a time evolution under two different values of an externally tunable parameter, allows for a high-fidelity ground state preparation in evolution times no longer than those required by the application of standard opti…
New trends in nonequilibrium statistical mechanics: classical and quantum systems
2020
The main aim of this special issue is to report recent advances and new trends in nonequilibrium statistical mechanics of classical and quantum systems, from both theoretical and experimental points of view, within an interdisciplinary context. In particular, the nonlinear relaxation processes in the dynamics of out-of-equilibrium systems and the role of the metastability and environmental noise will be overviewed. Three main areas of nonequilibrium statistical mechanics will be covered: slow relaxation phenomena and dissipative dynamics; long-range interactions and classical systems; quantum systems. New trends such as quantum thermodynamics and novel types of quantum phase transitions occ…
Effects of heat flux on lambda transition in liquid 4He,
2014
This paper is concerned with the derivation of a phase field model for λ-transition in 4He, when the liquid is subject to pressure and heat flux. As parameter that controls the transition, a field f that is the geometrical mean between the density of the fluid and that of the superfluid is used. The resulting model, that is a generalization of previous papers on the same subject, chooses as field variables the density, the velocity, the temperature and the heat flux, in addition to this field f. The restrictions on the constitutive quantities are obtained by using the Liu method of Lagrange multipliers. New results with respect to previous models are the presence of non-local terms to descr…